Self‐Organization of Oligomeric Helical Stacks Controlled by Substrate Binding in a Tobacco Mosaic Virus Like Self‐Assembly Process
Identifieur interne : 000329 ( Main/Exploration ); précédent : 000328; suivant : 000330Self‐Organization of Oligomeric Helical Stacks Controlled by Substrate Binding in a Tobacco Mosaic Virus Like Self‐Assembly Process
Auteurs : Anne Petitjean [États-Unis] ; Hélène Nierengarten [France] ; Alain Van Dorsselaer [France] ; Jean-Marie Lehn [France]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2004-07-12.
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Abstract
Selbstorganisation mit einem Dreh: Lineare Polyammoniumfäden sind die Template für die Anordnung helicaler heterocyclischer Bausteine zu Stapeln von Helices als Modell für das Tabakmosaikvirus. Die Länge des kationischen Substrats und der Abstand der positiven Ladungen im Faden bestimmen die Größe der resultierenden selbstorganisierten supramolekularen Architektur (siehe Bild).
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DOI: 10.1002/ange.200353492
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